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Více informací o knize Development of New Methods towards Guaiane Natural

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• Anotace
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Anotace knihy

Guaiane natural products are complex architectures that contain multiple stereogenic centers, ring junctures, and functionalities that render their synthesis difficult without an efficient and effective methodology. Herein, a new method for generating these natural products will be discussed. In particular, highly strained intermediates, generated through an intramolecular cyclobutadiene cycloaddition, will be studied and utilized. The following are a summary of the chapters:§Chapter 1: Tricyclo[3.2.0.02,4]heptanes are unique scaffolds that possess many interesting chemistries. A review of both their synthesis and chemistry is covered.§Chapter 2: Syn-tethered tetracyclo[5.3.0.01,5.02,4]decanes are strained systems obtained through a cyclobutadiene cycloaddition-intramolecular cyclopropanation sequence. Studies related to these systems will be covered.§Chapters 3 & 4: An intramolecular cyclobutadiene cycloaddition-cyclopropanation-thermal fragmentation methodology is utilized for the asymmetric total synthesis of two guaiane natural products. In addition, the methodology is further expanded upon to access multiple guaianes from a single intermediate.

Parametry knihy

Zařazení knihy Knihy v angličtině Mathematics & science Chemistry

• Plný název: Development of New Methods towards Guaiane Natural
• Autor: Michael Williams
• Jazyk: Angličtina
• Vazba: Brožovaná
• Počet stran: 420
• EAN: 9783836496414
• ISBN: 3836496410
• ID: 07148478
• Nakladatelství: VDM Verlag Dr. Mueller E.K.
• Hmotnost: 558 g
• Rozměry: 229 × 152 × 22 mm
• Datum vydání: 18. April 2008

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